Periodic Trends
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We will be discussing 4 trends found in the periodic table. We will first define them.
1.Atomic radius (size) – ½ the distance from center to center of two like atoms.
2.Ionization energy – the amount of energy needed to remove an electron from a specific atom or ion in its ground state
a.A + energy à A+ + e-
b.The amount of energy absorbed is equal to the ionization energy. It is an ENDOTHERMIC process, therefore, the number will always be positive.
3. Electronegativity – the ability of an atom to attract
Why??? As you move down any family, another principle energy level is added.
Decreases as you move from left to right within a period.
Why??? As the number of protons increase within the nucleus, the positive charge of the nucleus increases. As a result, the nucleus exerts a greater pull on all the electrons in the atom. Hence, pulling the electrons closer to the nucleus and decreasing the atomic size.
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Decreases as you move down a family.
Why??? The electrons that are removed from atoms of each succeeding element in a group are in a higher energy level. Therefore, since they are farther from the nucleus they receive less pull and are easily removed.
Increases as you move from left to right within a period.
Using Electronegativity Values in Bonding:
Subtracting the values of each element in a compound can indicate what type of bond exists between the elements.
If the difference in electronegativity is:
0 – 0.5 the bond is non-polar covalent
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This is the smallest e-neg value there is. This means the atom has very little ability to gain an electron. Instead, the atom loses an electron to obtain a 1+ charge.
What is the e-neg value of F?
This is the highest value. It means the atom attracts electrons very strongly. It will gain one electron o form a 1- ion.
The difference is 3.3. Therefore, the bond is ionic. This is a very strong bond.
Example:PH3
The e-neg value for P is
The e-neg value for H is
Both have equal e-neg values and attracting abilities. Therefore, neither element can take electrons away from the other. Therefore, they share the electrons equally. This is called a non-polar covalent bond.
Example:H2O
E-neg value for H:
E-neg value for O:
Difference: